STRONG REGIOCHEMICAL CONTROL OF BIMOLECULAR THERMOCHEMICAL REACTIONS IN CHOLESTERIC LIQUID-CRYSTALLINE SOLVENTS

被引：8

作者：

HIRAOKA, S ^{[1
]}

YOSHIDA, T ^{[1
]}

KANSUI, H ^{[1
]}

KUNIEDA, T ^{[1
]}

机构：

[1] KUMAMOTO UNIV,FAC PHARMACEUT SCI,OE HONMACHI,KUMAMOTO 862,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)74255-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Molecular ordering present in cholesteric liquid crystalline solvent phase is shown to be rigid enough to regulate the uncatalyzed Diels-Alder reactions conducted above 130-degrees-C with significantly high regioselectivity up to 90% d.e., which is considerably dependent on the structural features of reactants and the mesogens.

引用

页码：4341 / 4344

页数：4

共 19 条

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