POLYRADICALS - SYNTHETIC STRATEGIES AND CHARACTERIZATION

被引：7

作者：

CRAYSTON, JA ^{[1
]}

IRAQI, A ^{[1
]}

MALLON, P ^{[1
]}

WALTON, JC ^{[1
]}

TUNSTALL, DP ^{[1
]}

机构：

[1] UNIV ST ANDREWS, DEPT PHYS, ST ANDREWS KY16 9ST, FIFE, SCOTLAND

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

D O I：

10.1016/0379-6779(93)90166-T

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Synthetic routes to polyradicals are briefly reviewed; in addition the synthesis and electrochemical characterization of a novel anthraquinone derivatized thiophene monomer, 1-[4-(3-thienyl)butyl]2-anthraquinone carboxylate (I) is discussed. This monomer may be electropolymerized onto Pt in CH2Cl2 by successively more anodic potential sweeps from 0.0V, finally reaching a steady growth at a limit of +2.OV vs Ag+/0. The voltammogram of the resulting conducting polymer displays a polymer waves at Ep(a) + 1.0 and Ep(c) + 0.84V, and quinone waves at E0' = -0.80 and -1.24V vs Ag.+/0 The polymer is active towards O2 reduction in pH7 buffered aqueous solution.

引用

页码：867 / 872

页数：6

共 18 条

[1] ELECTRON-PARAMAGNETIC RESONANCE AND MAGNETIC-SUSCEPTIBILITY STUDIES OF NEW SUBSTITUTED POLY(ACETYLENE) DERIVATIVES
ALEXANDER, C
FEAST, WJ
FRIEND, RH
SUTCLIFFE, LH
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (04) : 459 - 465
[2] BEHAVIOR OF SOME POLY(PYRROLE-ANTHRAQUINONE) FILMS IN DMSO ELECTROLYTES
AUDEBERT, P
BIDAN, G
LAPKOWSKI, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 219 (1-2): : 165 - 181
[3] ELECTROCHEMICAL STUDY OF POLY(PHAS) IN ACETONITRILE AND WATER + ACETONITRILE ELECTROLYTES
AUDEBERT, P
BIDAN, G
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 238 (1-2): : 183 - 195
[4] THIOPHENES .1. FACILE SYNTHESIS OF 3-(OMEGA-HALOALKYL)THIOPHENES AS KEY BUILDING-BLOCKS FOR FUNCTIONALIZED THIOPHENES AND POLYTHIOPHENES
BAUERLE, P
WURTHNER, F
HEID, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (04) : 419 - 420
[5] BAUERLE P, 1990, ADV MATER, V2, P185
[6] BAUERLE P, 1991, SYNTHETIC MET, V41, P3037
[7] OXIDATIVE ELECTROPOLYMERIZATION OF POLYPYRIDINYL COMPLEXES OF RUTHENIUM(II)-CONTAINING PYRROLE GROUPS
COSNIER, S
DERONZIER, A
MOUTET, JC
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 193 (1-2): : 193 - 204
[8] TRIRUTHENIUM CLUSTER POLYPYRROLE FILMS - A REMARKABLY STABLE IMMOBILIZED RELAY AT HIGHLY POSITIVE POTENTIALS - ITS APPLICATION TO THE ELECTROCATALYTIC OXIDATION OF BENZYL ALCOHOL
COSNIER, S
DERONZIER, A
LLOBET, A
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 280 (01): : 213 - 219
[9] EPR STUDY OF PYRROLYL-1-OXYL AND 3-PYRROLINYL-1-OXYL RADICALS
CRAYSTON, JA
KAKOURIS, C
WALTON, JC
[J]. MAGNETIC RESONANCE IN CHEMISTRY, 1992, 30 (01) : 77 - 80
[10] CRAYSTON JA, UNPUB

← 1 2 →