IONIC CONDUCTION IN PURE AND DOPED SINGLE-CRYSTALLINE LITHIUM IODIDE

被引：36

作者：

JACKSON, BJH

YOUNG, DA

机构：

[1] Department of Chemical Engineering and Chemical Technology, Imperial College, London S.W. 7, England

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1969年 / 30卷 / 08期

关键词：

D O I：

10.1016/0022-3697(69)90174-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The free energy of defect formation and the activation energy for motion of the most mobile defect have been determined from the ionic conductivity of as-grown and Mg-doped single crystals of lithium iodide. Values obtained are sf = 4.5k, hf = 1.06 eV with km(cation vacancy) = 0.43 eV, giving a defect concentration at the melting point x0(Tm) = 0.18at.%, concordant with the other alkali halides. © 1969.

引用

页码：1973 / &

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