C3-HOMOLOGATION - SYNTHESIS OF C19-SKIPPED POLYENIC PHEROMONES

被引：12

作者：

VIALA, J

MUNIER, P

SANTELLI, M

机构：

[1] Laboratoire de Synthèse Organique, URA au CNRS no 1411. Faculté des Sciences, Saint Jérôme. 13397

来源：

TETRAHEDRON | 1991年 / 47卷 / 20-21期

关键词：

D O I：

10.1016/S0040-4020(01)86399-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Total synthesis of three sex pheromone components including an all-cis diene or triene unit are described. Starting from decanal, cis-Wittig reactions, by using C3 homologating agent 4 and convenient phosphonium salts, allowed us to built up all-cis skipped polyenic skeleton of the targets. These syntheses are shorter than those described in the literature and have been performed in better overall yield from starting materials.

引用

页码：3347 / 3352

页数：6

共 21 条

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