ELECTRONIC QUENCHING OF CH(A2-DELTA), NH(A3-PI), NH(C1-PI), AND PH(A3-PI) BETWEEN 240-K AND 420-K

被引：57

作者：

KENNER, RD ^{[1
]}

PFANNENBERG, S ^{[1
]}

HEINRICH, P ^{[1
]}

STUHL, F ^{[1
]}

机构：

[1] RUHR UNIV BOCHUM, W-4630 BOCHUM, GERMANY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 17期

关键词：

D O I：

10.1021/j100170a040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for electronic quenching of thermally equilibrated populations of CH(A), NH(A), NH(c), and PH(A) in upsilon = 0 by nine collision partners between 240 and 420 K have been measured. These data have been augmented by using literature values of electronic quenching rate constants for these and other diatomic hydrides. This body of data is then used to examine the general applicability of the various classical models and methods used by previous authors in individual cases.

引用

页码：6585 / 6593

页数：9

共 72 条

[1]

ALLEN JE, 1986, NBS SPEC PUBL, V716, P3

[2] LIFETIME MEASUREMENTS OF GEH AND CH IN THE A 2-DELTA, UPSILON'=0-STATE BY LASER-INDUCED FLUORESCENCE [J].