SOLUBILITY OF HYDROGEN IN A WHITE OIL

被引：25

作者：

SCHOFIELD, BA ^{[1
]}

RING, ZE ^{[1
]}

MISSEN, RW ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM ENGN & APPL CHEM,TORONTO M5S 1A4,ONTARIO,CANADA

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1992年 / 70卷 / 04期

关键词：

HYDROGEN SOLUBILITY; WHITE MINERAL OIL; DEPENDENCE ON PRESSURE AND TEMPERATURE; NORMAL-DECANE;

D O I：

10.1002/cjce.5450700431

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The solubility of hydrogen in a white mineral oil has been measured at pressures of 1.48 to 10.44 MPa at each of four temperatures (573. 603, 623, 643 K), in conjunction with a study of hydrodesulphurization in a trickle-bed reactor. The solubility varies from a hydrogen mole fraction of 0.056 at the lowest { T, P} to 0.262 at the highest. The solubility increases with increasing pressure and temperature. It can be represented by an equation suggested by using Krichevsky-Ilinskaya and van't Hoff expressions.

引用

页码：822 / 824

页数：3

共 12 条

[1] HYDROGEN SOLUBILITY IN COAL LIQUID (SRC-II) [J].

DING, FX ;

CHIANG, SH ;

KLINZING, GE .

FUEL, 1985, 64 (09) :1301-1305

[2] HYDROGEN SOLUBILITY IN ORGANIC LIQUIDS [J].

HERSKOWITZ, M ;

WISNIAK, J ;

SKLADMAN, L .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1983, 28 (02) :164-166

[3] SOLUBILITIES OF HYDROGEN AND METHANE IN COAL LIQUIDS [J].

LIN, HM ;

SEBASTIAN, HM ;

SIMNICK, JJ ;

CHAO, KC .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1981, 20 (02) :253-256

[4] SOLUBILITY OF HYDROGEN IN CREOSOTE OIL AT HIGH-TEMPERATURES AND PRESSURES [J].

PRATHER, JW ;

AHANGAR, AM ;

PITTS, WS ;

HENLEY, JP ;

TARRER, AR ;

GUIN, JA .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1977, 16 (03) :267-270

[5]

PRAUSNITZ JM, 1986, MOL THERMODYNAMICS F, P376

[6] TRICKLE-BED REACTORS - AN EXPERIMENTAL-STUDY OF PARTIAL WETTING EFFECT [J].

RING, ZE ;

MISSEN, RW .

AICHE JOURNAL, 1989, 35 (11) :1821-1828

[7] TRICKLE-BED REACTORS - EFFECT OF WETTING GEOMETRY ON OVERALL EFFECTIVENESS FACTOR [J].

RING, ZE ;

MISSEN, RW .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1986, 64 (01) :117-124

[8] TRICKLE-BED REACTORS - TRACER STUDY OF LIQUID HOLDUP AND WETTING EFFICIENCY AT HIGH-TEMPERATURE AND PRESSURE [J].

RING, ZE ;

MISSEN, RW .

CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1991, 69 (04) :1016-1020

[9]

SANDLER SI, 1989, CHEM ENG THERMODYNAM, P224

[10] GAS-LIQUID EQUILIBRIUM IN THE HYDROGEN + NORMAL-DECANE SYSTEM AT ELEVATED-TEMPERATURES AND PRESSURES [J].

SEBASTIAN, HM ;

SIMNICK, JJ ;

LIN, HM ;

CHAO, KC .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1980, 25 (01) :68-70

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