EXCITED-STATE PROPERTIES AND REACTIVITY OF [RECL(CO)3(2,2'-BIPY)] (2,2'-BIPY = 2,2'-BIPYRIDYL) STUDIED BY TIME-RESOLVED INFRARED-SPECTROSCOPY

被引：112

作者：

GEORGE, MW

JOHNSON, FPA

WESTWELL, JR

HODGES, PM

TURNER, JJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 19期

关键词：

D O I：

10.1039/dt9930002977

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fast time-resolved infrared spectroscopy shows that the nu(CO) bands of the important CO2-reducing complex, (ReCl(CO)3(2,2'-bipy)] 1 (2,2'-bipy = 2,2'-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1-, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the nu(CO) bands significantly different from those of related but non-reducing complexes.

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页码：2977 / 2979

页数：3

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