POLYNUCLEAR LANTHANIDE COMPLEXES - FORMATION OF A SELENIUM-CENTERED SM-6 COMPLEX, [((C(5)ME(5))SM)SE-6(11)]

被引：53

作者：

EVANS, WJ ^{[1
]}

RABE, GW ^{[1
]}

ANSARI, MA ^{[1
]}

ZILLER, JW ^{[1
]}

机构：

[1] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 20期

关键词：

D O I：

10.1002/anie.199421101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The central Se atom is surrounded by six (C5Me5)Sm units in a distorted octahedral arrangement in the title compounds (structure shown on the right). Four pairs of (Se2)2− units, the central Se atom, and two further Se atoms connect the six (C5Me5)Sm units. The complex contains a linear (Se3)4− moiety, which is isoelectronic with the (I3) ion. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：2110 / 2111

页数：2

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共 29 条

[1] SOLUBLE SELENIDES AND TELLURIDES [J].

ANSARI, MA ;

IBERS, JA .

COORDINATION CHEMISTRY REVIEWS, 1990, 100 :223-266

[2] A TRIVALENT RARE-EARTH COMPLEX OF THE HEAVIER CHALCOGENOLATES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(PY)2 YB(SEC6H5)2(MU-SEC6H5)2LI(PY)2] (PY = PYRIDINE) [J].

BERARDINI, M ;

EMGE, TJ ;

BRENNAN, JG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (20) :1537-1538

[3] ONE-DIMENSIONAL COORDINATION POLYMERS - [((PYRIDINE)2EU(MU-SEC6H5)2)4]INFINITY AND [(THF)3EU(MU-SEC6H5)2]INFINITY [J].

BERARDINI, M ;

EMGE, T ;

BRENNAN, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :8501-8502

[4] ELECTRON-TRANSFER REACTIONS OF DIVALENT YTTERBIUM METALLOCENES SYNTHESIS OF THE SERIES [(ME5C5)2YB]2[MU-O],[MU-S],[MU-SE],[MU-TE] AND CRYSTAL-STRUCTURE OF [(ME5C5)2YB]2[MU-SE] [J].

BERG, DJ ;

BURNS, CJ ;

ANDERSEN, RA ;

ZALKIN, A .

ORGANOMETALLICS, 1989, 8 (08) :1865-1870

[5] PREPARATION OF LANTHANIDE TELLUROLATES AND EVIDENCE FOR THE FORMATION OF CLUSTER INTERMEDIATES IN THEIR THERMAL-DECOMPOSITION TO BULK METAL TELLURIDES [J].

CARY, DR ;

ARNOLD, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (06) :2520-2521

[6] CRYSTAL-STRUCTURE OF 2-1 MOLECULAR-COMPLEXES OF CAFFEINE WITH HEXAAQUAMAGNESIUM(II) BROMIDE AND HEXAAQUAMANGANESE(II) TRIIODIDE IODIDE [J].

CINGI, MB ;

LANFREDI, AMM ;

TIRIPICCHIO, A ;

BANDOLI, G ;

CLEMENTE, DA .

INORGANICA CHIMICA ACTA-ARTICLES, 1981, 52 (02) :237-243

[7] THE STRUCTURAL CHEMISTRY OF METAL THIOLATE COMPLEXES [J].

DANCE, IG .

POLYHEDRON, 1986, 5 (05) :1037-1104

[8] ORGANOSAMARIUM-MEDIATED SYNTHESIS OF BISMUTH-BISMUTH BONDS - X-RAY CRYSTAL-STRUCTURE OF THE 1ST DIBISMUTH COMPLEX CONTAINING A PLANAR M2(MU-ETA-2-ETA-2-BI2) UNIT [J].

EVANS, WJ ;

GONZALES, SL ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (26) :9880-9882

[9] SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF AN UNSOLVATED, MONOMERIC BIS(PENTAMETHYLCYCLOPENTADIENYL) ORGANOLANTHANIDE COMPLEX, (C5ME5)2SM [J].

EVANS, WJ ;

HUGHES, LA ;

HANUSA, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (15) :4270-4272

[10] STRUCTURAL TRENDS IN BIS(PENTAMETHYLCYCLOPENTADIENYL)LANTHANIDE AND YTTRIUM COMPLEXES [J].

EVANS, WJ ;

FOSTER, SE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 433 (1-2) :79-94