STEREOCHEMISTRY OF QUATERNISATION OF 2-METHYL-2-AZABICYCLO[2,2,2]-OCT-5-ENE AND 1,2-DIMETHYL-1,2,3,6-TETRAHYDROPYRIDINE WITH TRIDEUTERIOMETHYL IODIDE

被引：4

作者：

BROWN, DR

MCKENNA, J

机构：

[1] Department of Chemistry, The University

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 05期

关键词：

D O I：

10.1039/j29690000570

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Quaternisation of 2-methyl-2-azabicyclo[2,2,2]oct-5-ene (I) and 1,2-dimethyl-1,2,3,6-tetrahydropyridine (II) with trideuteriomethyl iodide in ether proceeds with low stereoselectivity, the double bond having little effect on the preferred steric course of quaternisation. This is probably generally true for quaternisation of 1,2,3,6-tetrahydropyridines.

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页码：570 / &

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