FIBEROPTIC GLUCOSE SENSOR WITH ELECTROCHEMICAL GENERATION OF INDICATOR REAGENT

被引:16
作者
GUNASINGHAM, H
TAN, CH
SEOW, JKL
机构
[1] Department of Chemistry, National University of Singapore, Kent Ridge
关键词
D O I
10.1021/ac00206a022
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An electrochemlcally generated tetrathlafulvalene redox mediator provides a convenient and reversible indicator reagent for a glucose fiber-optic sensor. The fabrication and characterization of this sensor based on a thin-layer cell configuration are described. The performance of the fiber-optic sensor is compared with that of an amperometric enzyme electrode In flow-injection and steady-state analyses. The upper limit of the linear range In the flow-Injection mode is about 12 mM, whereas in the steady-state mode It Is about 3 mM. The sensor Is less prone to Interfering species and dissolved oxygen. It can be used continuously for 2 days without significant loss of activity. © 1990, American Chemical Society. All rights reserved.
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页码:755 / 759
页数:5
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