EXTRACTION OF NANOGRAM AMOUNTS OF CADMIUM AND OTHER METALS FROM AQUEOUS-SOLUTION USING HEXAMETHYLENEAMMONIUM HEXAMETHYLENEDITHIOCARBAMATE AS THE CHELATING AGENT

被引:25
作者
DORNEMANN, A
KLEIST, H
机构
[1] Bayer AG, Werk Uerdingen, AC-F Untersuchungslaboratorium
关键词
Atomic-absorption spectrometry; Dithiocarbamate chelation; Metal extraction; Nanogram amounts of metals;
D O I
10.1039/an9790401030
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A group of metals can be extracted from aqueous solution by using hexamethyleneammonium hexamethylenedithiocarbamate as the chelating agent and a mixture of 2,4-dimethylpentan-3-one and xylene as the organic phase. A description is given of a procedure for the determination of microgram and nanogram amounts of the nine metals silver, bismuth, cadmium, copper, nickel, lead, thallium and zinc in aqueous solution. The influence of a high content of iron and copper on the extraction is described.
引用
收藏
页码:1030 / 1036
页数:7
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