THE STEREOSELECTIVE CONSTRUCTION OF (Z)-3-ARYL-2-FLUOROALKENOATES

被引：50

作者：

WELCH, JT

HERBERT, RW

机构：

[1] Department of Chemistry, University at Albany, State University of New York, Albany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 16期

关键词：

D O I：

10.1021/jo00303a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: The use of 2,4,6-trimethylphenyl a-silyl-a-fluoroacetate in the Peterson olefination reaction leads to the highly stereoselective formation of (Z)-3-aryl-2-fluoroalkenoates via an aldol reaction most likely proceeding through an open transition state since stereocon-trol of the enolate geometry was not possible. © 1990, American Chemical Society. All rights reserved.

引用

页码：4782 / 4784

页数：3

共 51 条

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