SUPPRESSION OF THE METAL INSTABILITY AND CONTINUOUS CHANGE OF THE CARRIER DENSITY IN (MEBR-DCNQI)2CU1-XLIX

被引:27
作者
KOBAYASHI, H
MIYAMOTO, A
MORIYAMA, H
KATO, R
KOBAYASHI, A
机构
[1] UNIV TOKYO, INST SOLID STATE PHYS, MINATO KU, TOKYO 106, JAPAN
[2] UNIV TOKYO, FAC SCI, DEPT CHEM, SAKYO KU, TOKYO 113, JAPAN
关键词
D O I
10.1246/cl.1991.863
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrical resistivities and IR spectra of new mixed cation (Cu/Li)-DCNQI systems were examined. (MeBr-DCNQI)2 Cu1-xLi(x) (0.25 < x < 0.5) remains in the metallic state down to 4 K. The stretching frequency of C = N(imine) of DCNQI shows a linear dependence on the charge of DCNQI, which is consistent with the mixed valency of Cu (Cu+1.3).
引用
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页码:863 / 866
页数:4
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