STRUCTURES OF POLYETHER COMPLEXES .7. SPHERICAL WRAPPING OF A LINEAR POLYETHER AROUND A CATION-1,20-BIS(8-QUINOLYLOXY)-3,6,9,12,15,18-HEXAOXAEICOSANE.RBI

被引：39

作者：

WEBER, G

SAENGER, W

VOGTLE, F

SIEGER, H

机构：

[1] MAX PLANCK INST EXPTL MED,CHEM ABT,HERMAN REIN STR 3,D-3400 GOTTINGEN,FED REP GER

[2] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-5300 BONN 1,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1002/anie.197902261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexs of very long polythers and alkali metal salts can be predicted to have two types of structures: 1) the polyether could wrap spherically around the cation and thus shield it from the anion, and 2) the polyether could adopt an S‐shaped arrangement with each loop coordinating a cation, which is still bound to an anion for geometric reasons. These two types have been accomplished in 1 (cation: Rb+) and 2 (salt: 2KSCN). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：226 / 227

页数：2

共 16 条

[1] MACROCYCLIC POLYETHER SULFIDE SYNTHESES - PREPARATION OF THIA(CROWN-6, CROWN-7 AND CROWN-8) COMPOUNDS [J].

BRADSHAW, JS ;

REEDER, RA ;

THOMPSON, MD ;

FLANDERS, ED ;

CARRUTH, RL ;

IZATT, RM ;

CHRISTENSEN, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (01) :134-136

[2] MACROCYCLIC OLIGO-ETHERS RELATED TO ETHYLENE-OXIDE [J].

DALE, J ;

KRISTIANSEN, PO .

ACTA CHEMICA SCANDINAVICA, 1972, 26 (04) :1471-+

[3] MOLECULAR AND MAGNETIC-STRUCTURE OF PARAMAGNETIC ION-PAIR BIS(TETRAGLYME)RUBIDIUM BIPHENYL, RB+[CH3O(CH2CH2O)4CH3]2C12H10- [J].

MOOIJ, JJ ;

KLAASSEN, AAK ;

BOER, ED ;

DEGENS, HML ;

VANDENHARK, TEM ;

NOORDIK, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (03) :680-685

[4]

SAENGER W, ACTA CRYSTALLOGR

[5]

SAENGER W, 1977, METAL LIGAND INTER 1, P363

[6] ALKALINE-EARTH METAL-COMPLEXES OF SIMPLE OLIGO(ETHYLENE GLYCOL ETHERS) [J].

SIEGER, H ;

VOGTLE, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (03) :198-199

[7]

SIEGER H, 1978, ANGEW CHEM, V90, P212

[8] STRUCTURES OF POLYETHER COMPLEXES .3. MOLECULAR AND CRYSTAL-STRUCTURE OF BIS[(ORTHO-METHOXYPHENOXY)ETHOXY]ETHANE-SODIUM ISOTHIOCYANATE [J].

SUH, IH ;

WEBER, G ;

SAENGER, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (SEP) :2752-2756

[9] NONCYCLIC CROWN ETHERS - TERMINAL GROUP CONCEPT [J].

VOGTLE, F ;

SIEGER, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (06) :396-398

[10]

VOGTLE F, 1978, J CHEM RES-S, P398

← 1 2 →