PHOTOOXIDATION OF [RE2(CO)10] IN LOW-TEMPERATURE MATRICES CONTAINING O-2

被引：12

作者：

ALMOND, MJ

ORRIN, RH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 07期

关键词：

D O I：

10.1039/dt9920001229

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photo-oxidation of [Re2(CO)10] isolated in low-temperature matrices containing O2 generates, alongside free CO and CO2, the binary oxide Re2O7. The reaction appears to be initiated by Re-Re bond cleavage and proceeds via at least two detectable oxorhenium carbonyl species. Infrared spectroscopic studies, including isotopic substitution with O-18 and C-13, suggest that these intermediates are most likely to be (OC)5Re-O-O-Re(CO), and O = Re(CO)5.

引用

收藏

页码：1229 / 1234

页数：6

相关论文

共 48 条

[1] PRODUCTION OF BINARY OXIDES BY PHOTOLYSIS OF M(CO)6 MOLECULES (M = CR, MO, OR W) ISOLATED IN O-2-DOPED ARGON MATRICES [J].

ALMOND, MJ ;

DOWNS, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (04) :809-817

[2] FORMATION OF MOLECULAR CHROMIUM(IV) OXIDE (CRO2) BY PHOTOLYSIS OF CR(CO)6 IN O-2-DOPED ARGON MATRICES [J].

ALMOND, MJ ;

HAHNE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (09) :2255-2260

[3] PEROXO AND DIOXO METAL-CARBONYL INTERMEDIATES IN THE PHOTOOXIDATION OF MATRIX-ISOLATED CR(CO)6, MO(CO)6, W(CO)6 IN THE PRESENCE OF DIOXYGEN - A VIBRATIONAL SPECTROSCOPIC STUDY USING O-18 [J].

ALMOND, MJ ;

CRAYSTON, JA ;

DOWNS, AJ ;

POLIAKOFF, M ;

TURNER, JJ .

INORGANIC CHEMISTRY, 1986, 25 (01) :19-25

[4] FORMATION OF DIMANGANESE HEPTOXIDE, MN2O7, BY PHOTOLYSIS OF MN2(CO)10 IN O2-DOPED ARGON MATRICES [J].

ALMOND, MJ .

JOURNAL OF MOLECULAR STRUCTURE, 1988, 172 :157-164

[5]

ALMOND MJ, UNPUB

[6]

AYMONINO PJ, 1967, Z NATURFORSCH B, V24, P1508

[7] A MASS SPECTROMETRIC STUDY OF RHENIUM-OXYGEN SYSTEM [J].

BATTLES, JE ;

GUNDERSE.GE ;

EDWARDS, RK .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12) :3963-&

[8] METHYLTRIOXORHENIUM - AIR-STABLE COMPOUND CONTAINING A CARBON-RHENIUM BOND [J].

BEATTIE, IR ;

JONES, PJ .

INORGANIC CHEMISTRY, 1979, 18 (08) :2318-2319

[9] VIBRATIONAL SPECTRUM OF GASEOUS, LIQUID, AND SOLID RE2O7 [J].

BEATTIE, IR ;

OZIN, GA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (17) :2615-&

[10] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [RE(MU-O)2O2(CH2CME3)4] AND THE LI+ AND [NET4]+ SALTS OF THE D2 [REO2(CH2CME3)2]- ANION [J].

CAI, S ;

HOFFMAN, DM ;

HUFFMAN, JC ;

WIERDA, DA ;

WOO, HG .

INORGANIC CHEMISTRY, 1987, 26 (22) :3693-3700

← 1 2 3 4 5 →