EFFECT OF BIPHENYL AND NAPHTHYL GROUPS ON THE STRUCTURE OF SELF-ASSEMBLED MONOLAYERS - PACKING, ORIENTATION, AND WETTING PROPERTIES

被引：88

作者：

TAO, YT

LEE, MT

CHANG, SC

机构：

[1] Institute of Chemistry, Academia Sinica, Taipei, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 21期

关键词：

D O I：

10.1021/ja00074a020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembling behavior of a series of 4-alkoxybiphenyl-4'-carboxylic acid and 6-alkoxy-2-naphthoic acid compounds on the surfaces of Ag and Cu was studied. The structure of the monolayer film was probed with ellipsometry, reflection absorption IR spectroscopy, and contact angle measurements. The effect of aromatic chromophores on the packing, orientation of the molecular assembly, and wetting properties of the monolayer film was investigated. These monolayer structures were compared with those of n-alkanoic acids and n-alkanethiols to deduce the packing mechanism of carboxylic acid adsorption on metal oxides.

引用

页码：9547 / 9555

页数：9

共 46 条

[1] SPONTANEOUSLY ORGANIZED MOLECULAR ASSEMBLIES .1. FORMATION, DYNAMICS, AND PHYSICAL-PROPERTIES OF NORMAL-ALKANOIC ACIDS ADSORBED FROM SOLUTION ON AN OXIDIZED ALUMINUM SURFACE [J].