SPECTROELECTROCHEMICAL AND KINETIC-BEHAVIOR OF THE [RU(EDTA)-(DIETHYLDITHIOCARBAMATE)] COMPLEX

被引：11

作者：

ARAKI, K ^{[1
]}

REIN, FN ^{[1
]}

CAMERA, SG ^{[1
]}

TOMA, HE ^{[1
]}

机构：

[1] UNIV SAO PAULO,INST QUIM,CAIXA POSTAL 20780,BR-01498 SAO PAULO,BRAZIL

来源：

TRANSITION METAL CHEMISTRY | 1992年 / 17卷 / 06期

关键词：

D O I：

10.1007/BF02910752

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Ru(edta)(ddtc)]2- complex, where ddtc- represents a bidentate diethyldithiocarbamate ligand, has been characterized in one solid state and in solution. Reversible electrochemical and spectroelectrochemical behaviour has been observed for the complex, with E0(Ru(III)/Ru(II)) = -0.22 V versus S.H.E. A formation mechanism starting from [RuIII(edta)(H2O)]- and ddtc- is proposed, involving a monodentate binding step, with k(f) = 17 M-1 s-1, followed by rapid ring closure.

引用

页码：535 / 538

页数：4

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