BICHEP - RU COMPLEXES, HIGHLY EFFICIENT CATALYSTS FOR ASYMMETRIC HYDROGENATION OF CARBONYL-COMPOUNDS

被引：44

作者：

CHIBA, T

MIYASHITA, A

NOHIRA, H

TAKAYA, H

机构：

[1] SAITAMA UNIV,FAC ENGN,DEPT APPL CHEM,URAWA,SAITAMA 338,JAPAN

[2] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,KYOTO 60601,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)77611-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Newly prepared [RuX(p-cymene)(bichep)]X (X = I, Cl) and Ru(OAC)2(bichep) (bichep = 2,2'-bis(dicyclohexylphosphino)-6,6'-dimethyl-1,1'-biphenyl) proved to be highly efficient catalysts for asymmetric hydrogenation of carbonyl compounds bearing phenylglyoxyloyl group under mild conditions.

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页码：2351 / 2354

页数：4

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