IMINYLS .6. DIAZO-IMINYLS AND ALKOXY-IMINYLS

被引：15

作者：

FORRESTER, AR

GILL, M

MEYER, CJ

THOMSON, RH

机构：

[1] Chemistry Department, University of Aberdeen

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 03期

关键词：

D O I：

10.1039/p19790000637

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several diazo- and one alkoxy-aryliminyl(s) have been generated. These (i) fragment to arenecarbonitrile and aryl or alkoxyl radical, respectively, and (ii) abstract hydrogen to give the corresponding imines. The imines derived from the diazoiminyls react further to give triazoles and 2-aroylaminoazoarenes in low yield. Fragmentation of the phenyldiazoiminyls occurs more readily than that of the benzyloxyiminyl and the effect of α-substituents (phenyldiazo, benzyloxy, alkyl) on the ease of fragmentation of phenyliminyls is discussed.

引用

收藏

页码：637 / 642

页数：6

相关论文

共 33 条

[1] Studies on nitrosation, oximation and nitration of aldehydrazones. [J].

Bamberger, E ;

Pemsel, W .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1903, 36 :57-84

[2] ADDITIVITY RULES FOR ESTIMATION OF THERMOCHEMICAL PROPERTIES [J].

BENSON, SW ;

CRUICKSHANK, FR ;

GOLDEN, DM ;

HAUGEN, GR ;

ONEAL, HE ;

RODGERS, AS ;

SHAW, R ;

WALSH, R .

CHEMICAL REVIEWS, 1969, 69 (03) :279-+

[3] IMINYL RADICALS IN GAS-PHASE SYNTHESIS .1. GENERATION OF NITRILES BY PYROLYSIS OF ARYL AZINES [J].

BIRD, KJ ;

CHAN, AWK ;

CROW, WD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (10) :2281-2287

[4] A new route to 9-alkyl- and 9-arylanthracenes [J].

Bradsher, CK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :486-488

[5]

Bruckner A., 1880, LIEBIGS ANN CHEM, V205, P113

[6] NITROXIDE RADICALS .6. STABILITY OF META- AND PARA-ALKYL SUBSTITUTED PHENYL-T-BUTYLNITROXIDES [J].

CALDER, A ;

FORRESTE.AR .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (10) :1459-&

[7] IMINYL RADICALS IN GAS-PHASE SYNTHESIS .3. SYNTHESIS OF A TERMINALLY UNSATURATED NITRILE [J].

CROW, WD ;

MCNAB, H ;

PHILIP, JM .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (10) :2299-2306

[8] IMINYL RADICALS IN GAS-PHASE SYNTHESIS .2. FORMATION OF ALPHA-BRANCHED NITRILES FROM CYCLOALKANONE AZINES [J].

CROW, WD ;

KHAN, AN .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (10) :2289-2297

[9] IMINYLS .5. INTRA-MOLECULAR HYDROGEN ABSTRACTION BY ALKYL(ARYL)-IMINYLS - NEW TETRALONE SYNTHESIS [J].

FORRESTER, AR ;

GILL, M ;

NAPIER, RJ ;

THOMSON, RH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (03) :632-636

[10] IMINYLS .4. INTRA-MOLECULAR ABSTRACTION OF BENZYLIC HYDROGEN BY DIARYLIMINYLS [J].

FORRESTER, AR ;

GILL, M ;

THOMSON, RH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (03) :621-631

← 1 2 3 4 →