CROWNED-COUMARIN AS A NEW FLUORESCENCE DERIVATIZATION REAGENT FOR CARBOXYLIC-ACIDS

被引：11

作者：

TAKADATE, A ^{[1
]}

MASUDA, T ^{[1
]}

MURATA, C ^{[1
]}

TANAKA, T ^{[1
]}

MIYAHARA, H ^{[1
]}

GOYA, S ^{[1
]}

机构：

[1] KUMAMOTO UNIV, FAC PHARMACEUT SCI, KUMAMOTO 862, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 05期

关键词：

D O I：

10.1246/cl.1993.811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Bromoacetyl-6,7-[ 2',3'-( 1',4',7',10',13'-pentaoxacyclopentadeca )-2'-ene]--coumarin (2) was prepared as a new fluorescence derivatization reagent for carboxylic acids in high-performance liquid chromatographic analysis. The derivatization of lauric acid with 2 was readily accomplished under a quite mild condition to yield a highly fluorescent lauric acid derivative. The reaction was accelarated by combining crown moiety as a catalytic site to coumarin fluorophore.

引用

页码：811 / 814

页数：4

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