INCLUSION POLYMERIZATION WITHIN A TRIS(2,3-NAPHTHYLENEDIOXY)CYCLOTRIPHOSPHAZENE CLATHRATE

被引：28

作者：

ALLCOCK, HR

SILVERBERG, EN

DUDLEY, GK

PUCHER, SR

机构：

[1] Department of Chemistry, Pennsylvania State University, Pennsylvania 16802, University Park

来源：

MACROMOLECULES | 1994年 / 27卷 / 26期

关键词：

D O I：

10.1021/ma00104a008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The inclusion and Co-60 gamma-ray initiated polymerization of olefinic and acrylic monomers within the 10 Angstrom clathrate-tunnels formed by tris(2,3-naphthylenedioxy)cyclotriphosphazene is described. Methyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate, isoprene, dimethylbutadiene, acrylonitrile, and methacrylonitrile monomers were included by direct contact imbibition. The resultant polymers were characterized by H-1 and C-13 NMR spectroscopy, and the molecular weights were estimated by gel permeation chromatography and solution viscometry. The results are explained in terms of the host/synthesized previously within the 5 Angstrom tunnel of tris(o-phenylenedioxy)cyclotriphosphazene.

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收藏

页码：7550 / 7555

页数：6

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