The wittig reaction as a polymerization method

被引：121

作者：

Mcdonald, Richard N. ^{[1
]}

Campbell, Tod W. ^{[1
]}

机构：

[1] EI Du Pont Nemours & Co Inc, Textiles Fibers Dept, Pioneering Res Div, Wilmington, DE USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

p-Xylylene-bis-(triphenylphosphonium chloride) reacted with terephthalaldehyde in the presence of lithium ethylate to yield a decamer of poly-p-xylylidene (II, n = 9, X = CHO). Treatment of (2-methoxy-5-methylalbenzyl)-triphenylphosphonium chloride with base produced the methoxy derivative of poly-m-xylylidene (V), (p-Hydroxyphenyl)-triphenylphosphonium bromide on treatment with base failed to yield poly-p-phenylene.

引用

页码：4669 / 4671

页数：3

共 9 条

[1] AUSPOS CW, 1955, J POLYM SCI, V15, P10
[2] AROMATIC POLYHYDROCARBONS .1. MONOMER REACTIONS AND POLYMER PREPARATION
AUSPOS, LA
HALL, LAR
HUBBARD, JK
KIRK, WM
SCHAEFGEN, JR
SPECK, SB
[J]. JOURNAL OF POLYMER SCIENCE, 1955, 15 (79): : 9 - 17
[3] SYNTHESIS OF HYDROCARBON DERIVATIVES BY THE WITTIG SYNTHESIS .1. DISTYRYLBENZENES
CAMPBELL, TW
MCDONALD, RN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (09) : 1246 - 1251
[4] CHEMISTRY OF P-XYLYLENE, ITS ANALOGUES, AND POLYMERS
ERREDE, LA
SZWARC, M
[J]. QUARTERLY REVIEWS, 1958, 12 (04): : 301 - 320
[5] HORNER L, 1938, CHEM BER, V91, P52
[6] SYNTHESIS OF HYDROCARBON DERIVATIVES BY THE WITTIG REACTION .2. DIARYLBUTADIENES AND QUINQUEPHENYLS
MCDONALD, RN
CAMPBELL, TW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (12) : 1969 - 1975
[7] Quelet R, 1937, CR HEBD ACAD SCI, V205, P238
[8] TRIPHENYLPHOSPHONIUM SALTS
SHELDON, JC
TYREE, SY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (09) : 2117 - 2120
[9] THE DIRECT MICRO-DETERMINATION OF OXYGEN IN ORGANIC SUBSTANCES
UNTERZAUCHER, J
[J]. ANALYST, 1952, 77 (920) : 584 - +

← 1 →