AN ELECTROCHEMICAL INVESTIGATION OF THE 1-METHYL-3-ETHYLIMIDAZOLIUM BROMIDE ALUMINUM BROMIDE MOLTEN-SALT SYSTEM

被引：12

作者：

BOON, JA ^{[1
]}

WILKES, JS ^{[1
]}

LANNING, JA ^{[1
]}

机构：

[1] UNIV COLORADO,DENVER,CO 80204

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1991年 / 138卷 / 02期

关键词：

D O I：

10.1149/1.2085611

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical behavior of the room temperature molten salt made by combining 1-methyl-3-ethylimidazolium bromide and aluminum bromide was studied. It was found that the bromide system behaved, for the most part, analogously to the chloride counterpart. Bromide solvated in a room temperature molten salt is electrochemically similar to bromide in other nonaqueous solvent systems. The diffusion coefficients and the heterogeneous rate constants were determined for the bromide and tribromide species in the molten salt.

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页码：465 / 469

页数：5

相关论文

共 17 条

[1] SPECTROPHOTOMETRIC STUDY OF TETRABUTYLAMMONIUM TRIBROMIDE [J].

BUCKLES, RE ;

POPOV, AI ;

ZELEZNY, WF ;

SMITH, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (10) :4525-4528

[2]

CHATTAWAY FD, 1923, J AM CHEM SOC, V45, P654

[3] IONIC STRUCTURE AND INTERACTIONS IN 1-METHYL-3-ETHYLIMIDAZOLIUM CHLORIDE-ALCL3 MOLTEN-SALTS [J].

DIETER, KM ;

DYMEK, CJ ;

HEIMER, NE ;

ROVANG, JW ;

WILKES, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) :2722-2726

[4] A RECHARGEABLE CADMIUM-BROMINE BATTERY USING ROOM-TEMPERATURE CHLOROALUMINATE MOLTEN-SALTS [J].

DYMEK, CJ ;

REYNOLDS, GF ;

WILKES, JS .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (07) :1658-1663

[5]

GILBERT BP, 1986, NATO ASI SER, P213

[6]

Hurley F. H., 1948, United States Pat, Patent No. [2446331, 2 446 331]

[7] ALUMINUM BROMIDE-1-METHYL-3-ETHYLIMIDAZOLIUM BROMIDE IONIC LIQUIDS .2. TRANSPORT NUMBERS [J].

HUSSEY, CL ;

SANDERS, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (8A) :1977-1980

[8] KINETICS OF BROMINE-TRIBROMIDE-BROMIDE REDOX PROCESSES ON PLATINUM ELECTRODES IN ACETONITRILE SOLUTIONS [J].

IWASITA, T ;

GIORDANO, MC .

ELECTROCHIMICA ACTA, 1969, 14 (10) :1045-&

[9]

KISSINGER PT, 1984, LABORATORY TECHNIQUE

[10] REACTION OF CHLORIDE-IONS IN LOW-TEMPERATURE MOLTEN-SALTS AND APPLICATION TO THE STUDY OF COMPLEX ION STOICHIOMETRY [J].

LIPSZTAJN, M ;

OSTERYOUNG, RA .

INORGANIC CHEMISTRY, 1984, 23 (12) :1735-1739