NITRILE ADDITION TO TRICARBONYLCYCLOHEXADIENYLIUM COMPLEXES - THE EFFECT OF PERCHLORATE COUNTERANION

被引：8

作者：

ONG, CW

CHAO, YK

CHANG, YA

机构：

[1] Department of Chemistry, National Sun Yat Sen University, Kaoshiung

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73417-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for the preparation of the tricarbonylcylohexadienyliumiron perchlorate salt and their reactions with TMS-CN were investigated. The nucleophilic addition reactions of TMS-CN were insensitive to the perchlorate counteranion since it cannot dissociate into a nucleophlilic species to release the free cyanide anion. A reductive workup was developed to avoid decompositions.

引用

页码：6303 / 6304

页数：2

共 6 条

[1] A SUPERIOR METHOD FOR THE ADDITION OF CYANIDE TO SUBSTITUTED TRICARBONYL(ETA-5-CYCLOHEXADIENYL)IRON(1+) SALTS [J].