CHARACTERIZATION OF THE IONIZATION AND SPECTRAL PROPERTIES OF SULFONEPHTHALEIN INDICATORS - CORRELATION WITH SUBSTITUENT EFFECTS AND STRUCTURAL FEATURES

被引：31

作者：

CASULA, R

CRISPONI, G

CRISTIANI, F

NURCHI, V

CASU, M

LAI, A

机构：

[1] DIPARTIMENTO CHIM & TECNOL INORGAN & MET ORGAN,VIA OSPED 72,I-09124 CAGLIARI,ITALY

[2] DIPARTIMENTO SCI CHIM,I-09124 CAGLIARI,ITALY

来源：

TALANTA | 1993年 / 40卷 / 12期

关键词：

D O I：

10.1016/0039-9140(93)80097-B

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The pK values of the second ionization of a set of substituted sulfonephthaleins are studied by spectrophotometry and C-13 NMR spectroscopy. A study of the correlation between equilibrium and spectral data on the one hand and the substituent effects on the other is presented, using the dual substituent analysis of Swain and Lupton. This shows a complete dependence of pK values on the F field variable, and of the wavelengths of the bands of basic forms on the R resonance variable.

引用

页码：1781 / 1788

页数：8

共 30 条

[1] KINETICS AND EQUILIBRIA IN THE REDOX REACTION BETWEEN ETHYLENEDINITRILOTETRA-ACETATE COMPLEXES OF IRON(III) AND VANADIUM(III) IN AQUEOUS-SOLUTION
AHMAD, JAM
HIGGINSON, WCE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (07): : 1449 - 1459
[2] BEUKENKAMP J, 1975, TREATISE ANALYTICAL, V11, pCH115
[3] MIXED-LIGAND COMPLEX-FORMATION IN THE COPPER(II)-SALICYLATE-AMMONIA AND IN THE COPPER(II)-SALICYLATE-PYRIDINE SYSTEMS
CASASSAS, E
TAULER, R
[J]. JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1985, 82 (11-12) : 1067 - 1078
[4] ON THE POSSIBILITY OF DETERMINING THE THERMODYNAMIC PARAMETERS FOR THE FORMATION OF WEAK COMPLEXES USING A SIMPLE-MODEL FOR THE DEPENDENCE ON IONIC-STRENGTH OF ACTIVITY-COEFFICIENTS - NA+, K+, AND CA-2+ COMPLEXES OF LOW-MOLECULAR WEIGHT LIGANDS IN AQUEOUS-SOLUTION
DANIELE, PG
DEROBERTIS, A
DESTEFANO, C
SAMMARTANO, S
RIGANO, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (11): : 2353 - 2361
[5] THE THERMODYNAMICS OF COMPLEXING OF LN(III) AND AM(III) BY CHLOROACETATES
ENSOR, DD
CHOPPIN, GR
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1980, 42 (10): : 1477 - 1480
[6] CALCULATION OF EQUILIBRIUM-CONSTANTS FROM MULTIWAVELENGTH SPECTROSCOPIC DATA .4. MODEL-FREE LEAST-SQUARES REFINEMENT BY USE OF EVOLVING FACTOR-ANALYSIS
GAMPP, H
MAEDER, M
MEYER, CJ
ZUBERBUHLER, AD
[J]. TALANTA, 1986, 33 (12) : 943 - 951
[7] CALCULATION OF EQUILIBRIUM-CONSTANTS FROM MULTIWAVELENGTH SPECTROSCOPIC DATA .3. MODEL-FREE ANALYSIS OF SPECTROPHOTOMETRIC AND ELECTRON-SPIN-RESONANCE TITRATIONS
GAMPP, H
MAEDER, M
MEYER, CJ
ZUBERBUHLER, AD
[J]. TALANTA, 1985, 32 (12) : 1133 - 1139
[8] QUANTIFICATION OF A KNOWN COMPONENT IN AN UNKNOWN MIXTURE
GAMPP, H
MAEDER, M
MEYER, CJ
ZUBERBUEHLER, AD
[J]. ANALYTICA CHIMICA ACTA, 1987, 193 : 287 - 293
[9] AN INVESTIGATION ON THE INTERACTION BETWEEN PALLADIUM(II) AND L-CITRULLINE BY H-1 AND C-13 NMR-SPECTROSCOPY AND POTENTIOMETRY
GANADU, ML
LEONI, V
CRISPONI, G
NURCHI, V
[J]. POLYHEDRON, 1991, 10 (03) : 333 - 336
[10] DETERMINATION OF THE EQUIVALENCE POINT IN POTENTIOMETRIC TITRATIONS .2.
GRAN, G
[J]. ANALYST, 1952, 77 (920) : 661 - 671

← 1 2 3 →