SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE [NB(O)(S-2)(2)SH](2-), [NB(S)(3)SH](2-), AND ([NB(S)(3)]O-2)(4-) ANIONS - NEW ELEMENTARY THIONIOBATES AND OXOTHIONIOBATES

被引：22

作者：

MANDIMUTSIRA, BS ^{[1
]}

CHEN, SJ ^{[1
]}

DEMADIS, KD ^{[1
]}

COUCOUVANIS, D ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 09期

关键词：

D O I：

10.1021/ic00113a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of three new elementary chalcogenometallates is reported. The [(O)Nb(S-2)(2)(SH)](2-) and {[Nb(S)(3)](2)(mu-O)}(4-) anions have been obtained in the reactions of the [Nb(S)(3)(S(t)Bu)](2-) anion with elemental sulfur and Et(3)N respectively in the presence of water. The [(O)Nb(S-2)(2)(SB)](2-) anion reacts with Et(3)P to give the [Nb(S)(3)(SH)](2-) anion. [GRAPHICS]

引用

页码：2267 / 2268

页数：2

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