ABINITIO STUDIES OF A MARGINALLY STABLE INTERMEDIATE IN THE BASE-CATALYZED METHANOLYSIS OF DIMETHYL-PHOSPHATE AND NONEXISTENCE OF THE STEREOELECTRONICALLY UNFAVORABLE TRANSITION-STATE

被引：69

作者：

UCHIMARU, T ^{[1
]}

TANABE, K ^{[1
]}

NISHIKAWA, S ^{[1
]}

TAIRA, K ^{[1
]}

机构：

[1] MINIST INT TRADE & IND,AGCY IND SCI & TECHNOL,FERMENTAT RES INST,TSUKUBA 305,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 11期

关键词：

D O I：

10.1021/ja00011a060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：4351 / 4353

页数：3

共 13 条

[1] ON THE MECHANISM OF CATALYSIS BY RIBONUCLEASE - CLEAVAGE AND ISOMERIZATION OF THE DINUCLEOTIDE UPU CATALYZED BY IMIDAZOLE BUFFERS [J].

ANSLYN, E ;

BRESLOW, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) :4473-4482

[2] SEQUENTIAL GENERAL BASE ACID CATALYSIS IN THE HYDROLYSIS OF RNA BY IMIDAZOLE [J].

BRESLOW, R ;

LABELLE, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (10) :2655-2659

[3] DIANIONIC PENTACOORDINATE SPECIES IN THE BASE-CATALYZED-HYDROLYSIS OF ETHYLENE AND DIMETHYL-PHOSPHATE [J].

DEJAEGERE, A ;

LIM, C ;

KARPLUS, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) :4353-4355

[4]

Deslongchamps P., 1983, STEREOELECTRONIC EFF

[5] STEREOELECTRONIC EFFECTS IN BIOMOLECULES [J].

GORENSTEIN, DG .

CHEMICAL REVIEWS, 1987, 87 (05) :1047-1077

[6] STEREOELECTRONIC EFFECTS IN THE REACTIONS OF PHOSPHATE DIESTERS - ABINITIO MOLECULAR-ORBITAL CALCULATIONS OF REACTION SURFACES .2. [J].

GORENSTEIN, DG ;

LUXON, BA ;

FINDLAY, JB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (20) :5869-5875

[7] NONEXISTENCE OF DIANIONIC PENTACOVALENT INTERMEDIATES IN AN ABINITIO STUDY OF THE BASE-CATALYZED-HYDROLYSIS OF ETHYLENE PHOSPHATE [J].

LIM, C ;

KARPLUS, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (15) :5872-5873

[8]

STORER JW, IN PRESS J AM CHEM S

[9] STEREOELECTRONIC EFFECTS ON THE BASICITY AND NUCLEOPHILICITY OF PHOSPHITES AND PHOSPHATES - ABINITIO MOLECULAR-ORBITAL CALCULATIONS AND THE ALPHA-EFFECT [J].

TAIRA, K ;

GORENSTEIN, DG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (25) :7825-7831

[10] ENERGETICS OF RNA CLEAVAGE - IMPLICATIONS FOR THE MECHANISM OF ACTION OF RIBOZYMES [J].

TAIRA, K ;

UEBAYASI, M ;

MAEDA, H ;

FURUKAWA, K .

PROTEIN ENGINEERING, 1990, 3 (08) :691-701

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