REACTIONS OF THE RU METHOXO COMPLEX .6. LIGAND-EXCHANGE DURING COMPLEXING DEPROTONATION TO AND MOLECULAR-STRUCTURE OF H4-1,5-CYCLOOCTADIENE)(H6-1,2,3,4-TETRAMETHYLFULVENE)RUTHENIUM

被引：26

作者：

KOLLE, U ^{[1
]}

KANG, BS ^{[1
]}

THEWALT, U ^{[1
]}

机构：

[1] UNIV ULM,SEKT RONTGEN & ELEKTRONENBEUGUNG,W-7900 ULM,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85252-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study of Cl/OMe exchange reactions in the complexes [Cp{black star}RuOMe]2 (1)/[Cp{black star}RuCl]4 (2) and in Cp{black star}Ru(COD)Cl (3) indicates that a deprotonation or HCl elimination from 3 by LiOR yields the fulvene complex Ru(C5Me4-exo- CH2)(COD) (4). The molecular structure of 4, as determined by single crystal X-ray diffraction, reveals a bent h6-fulvene ligand with short (2.323(7) Å) Ru-exo-CH2 distance. © 1990.

引用

页码：267 / 273

页数：7

共 14 条

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[5] REACTIONS OF THE RU METHOXO COMPLEX .5. CONVERSION OF AN ORGANOMETALLIC ALKOXO LIGAND INTO A HYDRIDO LIGAND, FORMATION AND MOLECULAR-STRUCTURE OF CP]RU(COD)H
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[6] PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM-ALKOXO COMPLEXES .3. COMPARATIVE MOLECULAR-STRUCTURE OF [CP-STAR-RUOME]2 AND [(CP-STAR-RW)3(MU3-OME)2]PF6
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[8] KOLLE U, 1989, J ORGANOMET CHEM, V362, P383
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[10] KOSSAKOWSKI J, 1989, THESIS RWTH AACHEN

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