EFFECTIVE 1,7-ASYMMETRIC INDUCTION IN REACTIONS BETWEEN 6-HYDROXYALLYLSTANNANES AND ALDEHYDES PROMOTED BY TIN(IV) BROMIDE

被引：29

作者：

CAREY, JS ^{[1
]}

THOMAS, EJ ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000283

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transmetallation of tributyl[(6R)-6-hydroxyhept-2-enyl]stannane 7 by tin(IV) bromide generates an allyltin tribromide which reacts with aldehydes to give 1-substituted 1,7-dihydroxyoct-3-enes with effective 1,7-asymmetric induction.

引用

页码：283 / 284

页数：2

共 16 条

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