A NOVEL SLIPPED TRIPLE-DECKER COMPLEX WITH A 3,4-DIBORAFULVENE AS BRIDGING LIGAND

被引:5
作者
HERBERICH, GE [1 ]
GANTER, C [1 ]
WESEMANN, L [1 ]
BOESE, R [1 ]
机构
[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY
关键词
D O I
10.1016/0022-328X(90)87269-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of the 3,4-diboratafulvene derivative Li2[CH2C{CHB(NEt2)}2] with [RhCl(COD)]2 gives μ-[1-5-η5 : 1,2,5,6-η4-{CH2C[CHB(NEt2)]2}][Rh(η-COD)]2 (V), the first 3,4-diborafulvene complex. V possesses a doubly-opened triple-decker structure with a bridging 3,4-diborafulvene ligand. © 1990.
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页码:C1 / C5
页数:5
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