TETRAHEDRAL GUEST IN A TETRAHEDRAL CAVITY - A NEOPENTANE MOLECULE ENCAGED IN A 3-DIMENSIONAL CADMIUM CYANIDE FRAMEWORK

被引：65

作者：

KITAZAWA, T ^{[1
]}

NISHIKIORI, S ^{[1
]}

YAMAGISHI, A ^{[1
]}

KURODA, R ^{[1
]}

IWAMOTO, T ^{[1
]}

机构：

[1] UNIV TOKYO,COLL ARTS & SCI,DEPT CHEM,TOKYO 153,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 05期

关键词：

D O I：

10.1039/c39920000413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mineralomimetic three-dimensional framework of cadmium cyanide, like cristobalite or cubic ice, enchlathrates a neopentane (2,2-dimethylpropane) molecule with an orientation such that the respective C-Me bonds direct toward the tetrahedral corners of the adamantane-like cage cavity, whereas carbon tetrachloride encaged in the same host distributes the C-Cl bonds statistically about the threefold axis of the cubic crystal.

引用

页码：413 / 415

页数：3

共 12 条

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