ACTIVITY OF SUBSTRATES IN THE CATALYZED NUCLEATION OF GLASS-FORMING MELTS .2. EXPERIMENTAL-EVIDENCE

被引:234
作者
DOBREVA, A [1 ]
GUTZOW, I [1 ]
机构
[1] BULGARIAN ACAD SCI,INST PHYS CHEM,BU-1040 SOFIA,BULGARIA
关键词
D O I
10.1016/0022-3093(93)90737-I
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Methods for determining the nucleating activity of substrates are considered. Experimental data on the activity of nucleating catalysts in various organic and inorganic glass-forming melts are summarized and discussed in terms of the theoretical approach developed in Part I of the present investigation. The nucleation of the same melt induced by different substrates is analyzed. In this respect, the data for sodium metaphosphate, lithium metaphosphate. poly(ethylene terephthalate), poly(vinyl chloride), sodium tetraborate nucleated with noble metal cores, for poly(decamethylene terephthalate), lithium disilicate, poly(ethylene) and water initiated by oxide and halide catalysts give a direct proof for the validity of the concepts, developed in Part I.
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页码:13 / 25
页数:13
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