ROTATIONAL-ISOMERISM IN BIS(CARBON DIOXIDE) COMPLEXES OF MOLYBDENUM GENERATED BY CONROTATORY MOTION OF THE CO2 LIGANDS

被引：18

作者：

CARMONA, E

MUNOZ, MA

PEREZ, PJ

POVEDA, ML

机构：

[1] Departamento de Química Inorgánica-Instltuto de Ciencia de Materiales, Universidad de Sevilla-CSIC, Apdo. 553

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a077

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The existence of rotational isomers in (CO2)2 complexes of molybdenum and their interconversion by a concerted rotation, in which the two CO2 ligands rotate in the same direction, have been demonstrated with the aid of variable-temperature NMR studies carried out with complexes of the type frans-[Mo(CO2)2(PMe3)2(P-P)] and trans-[Mo(CO2)2(P-P)2] (P-P = chelating diphosphine). © 1990, American Chemical Society. All rights reserved.

引用

页码：1337 / 1339

页数：3

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