OXIDATIVE ADDITION TO 3,6-DEHYDROHOMOADAMANTANE

被引：10

作者：

FOKIN, AA

GUNCHENKO, PA

YAROSHINSKY, AI

YURCHENKO, AG

KRASUTSKY, PA

机构：

[1] Department of Chemical Technology, Kiev Polytechnic Institute

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 25期

关键词：

PROPELLANE; ADDITION; OXIDATION;

D O I：

10.1016/0040-4039(95)00763-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transformations of 3,6-dehydrohomoadamantane (1) and 1,3-dehydroadamantane (2) with nitronium reagents were studied. In the case of compound 1 an oxidative route of reaction is realized resulting in addition of two nucleophiles from reagent or solvent to the strained C-C bond. Contrary to this, compound 2 in the same conditions undergoes an electrophilic addition reaction.

引用

页码：4479 / 4482

页数：4

共 10 条

[1] PARTIAL ANODIC-OXIDATION OF NORMAL ALKANES IN ACETONITRILE AND TRIFLUOROACETIC ACID [J].