X-RAY PHOTOELECTRON-SPECTRA OF TI4+ IN TIO2.EVIDENCE OF BAND-STRUCTURE

被引：37

作者：

SCROCCO, M ^{[1
]}

机构：

[1] UNIV ROME,IST CHIM,I-00100 ROME,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 61卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)87148-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Satellite structure has been observed at about 3.1, 5.4, 6.4 and 14.5 eV below the main peaks in the X-ray photoelectron spectra of the Ti and O levels of TiO2. These satellites arise from transitions, accompanying primary photoemission, between predominantly O2p states of the ligand and various excited states in the conduction band. The energies found fit the transitions calculated by Daude et al. for an electronic band structure calculated by a combined tight-binding and pseudopotential method. © 1979.

引用

页码：453 / 456

页数：4

共 16 条

[1] ELECTROABSORPTION IN RUTILE (TIO2) [J].