ABSOLUTE QUANTUM YIELDS FOR EXCIPLEX FLUORESCENCE

被引：8

作者：

HALE, SJ ^{[1
]}

MELTON, LA ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,RICHARDSON,TX 75083

来源：

APPLIED SPECTROSCOPY | 1990年 / 44卷 / 01期

关键词：

D O I：

10.1366/0003702904085895

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The absolute quantum yields for exciplex fluorescence in four solutions which have potential as exciplex-based vapor/liquid visualization systems have been measured. The room-temperature absolute quantum yields for 10% dibutyl-aniline/0.4%, 1-cyanonaphthalene, 12.5% 1-methylnaphthalene/0.5% N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD), 10% trihexylamine/1.0% 1-cyanonaphthalene, and 10% naphthalene/1.0% TMPD in hexadecane or cyclohexane are 0.03 ± 0.005, 0.05 ± 0.002 (308 nm), 0.02 ± 0.001, and 0.16 ± 0.021, respectively. The temperature dependence of the absolute quantum yield for the 10% naphthalene/1% TMPD in the hexadecane system was measured over the range of 23 to 260°C and was found to decrease by 20-30% at 260°C.

引用

页码：101 / 105

页数：5

共 33 条

[1]

[Anonymous], HDB FLUORESCENCE SPE

[2] FLUORESCENCE OF AZULENE AND 9,10-DIPHENYLANTHRACENE - REPLY TO CRITICISM [J].