PHASE-RELATIONS IN THE VXW1-XO2 SYSTEM (0.2 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 0.75)

被引:7
作者
NII, J
WAKIHARA, M
TANIGUCHI, M
机构
[1] Department of Chemical Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152, Ookayama
关键词
D O I
10.1016/0025-5408(79)90074-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The phase relations in the VxW1-xO2 system were studied by vacuum seal technique at 900°C. A new phase was found around composition of x=0.5. It has a slightly distorted rutile-type structure with doubling of the a and c parameters of rutile. Phase transition from this phase to rutile-type phase was examined by DTA. Transition temperature increased with decreasing x-value. Enthalpy change for the transition and the variation of monoclinic angle of the phase seemed to have maximum values at composition of x=0.5. © 1979.
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页码:1069 / 1074
页数:6
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