ENCAPSULATION OF TIO2 IN ZEOLITE Y

被引:78
作者
LIU, XS [1 ]
IU, KK [1 ]
THOMAS, JK [1 ]
机构
[1] UNIV NOTRE DAME,DEPT CHEM & BIOCHEM,NOTRE DAME,IN 46556
关键词
D O I
10.1016/0009-2614(92)86129-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new method of incorporating TiO2 into zeolite cavities through ion exchange of zeolites Y with an aqueous solution of ammonium titanyl oxalate oxalate monohydrate, (NH4)2TiO(C2O4)2H2O, has been developed. Characterization of the products clearly demonstrates that (1) ion exchange between the Ti species present in the solution and the cations in the zeolities takes place; (2) the Ti species are located inside the zeolite cavities, but not on the external surface of the zeolite; and (3) the Ti-species encapsulated are TiO2 clusters of various small particles sizes and have characteristics of the TiO2 semiconductor.
引用
收藏
页码:163 / 168
页数:6
相关论文
共 17 条
[2]   PHOTOLUMINESCENCE AND PHOTOCATALYTIC ACTIVITY OF HIGHLY DISPERSED TITANIUM-OXIDE ANCHORED ONTO POROUS VYCOR GLASS [J].
ANPO, M ;
AIKAWA, N ;
KUBOKAWA, Y ;
CHE, M ;
LOUIS, C ;
GIAMELLO, E .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (23) :5017-5021
[3]  
AUGUSTYNSKI J, 1988, STRUCT BOND, V69, P1
[4]   SOME REACTIONS OF TIN OXIDE CHLORIDE AND TITANIUM OXIDE CHLORIDE [J].
BEATTIE, IR ;
FAWCETT, V .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (10) :1583-&
[7]  
FAN FRF, 1985, J PHYS CHEM-US, V85, P4418
[8]  
IU KK, 1991, MATER RES SOC SYMP P, V233, P119, DOI 10.1557/PROC-233-119
[9]  
JEFFERY PG, 1981, CHEM METHOD ROCK ANA, P345
[10]  
KRUEGER JS, 1990, INCLUSION PHENOMENON, P365