ELECTRICAL-CONDUCTIVITY OF POLY(PARA-PHENYLENE VINYLENE) FILMS DOPED WITH FECL3

被引：7

作者：

MERTENS, R ^{[1
]}

NAGELS, P ^{[1
]}

CALLAERTS, R ^{[1
]}

BRIERS, J ^{[1
]}

GEISE, HJ ^{[1
]}

机构：

[1] UNIV INSTELLING ANTWERP,DEPT CHEM,B-2610 WILRIJK,BELGIUM

来源：

SYNTHETIC METALS | 1993年 / 57卷 / 01期

关键词：

D O I：

10.1016/0379-6779(93)90472-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Highly oriented films of poly(p-phenylene vinylene), PPV, were prepared by uniaxial stressing during the thermal conversion of a sulphonium polyelectrolyte precursor polymer. The molecular orientation is studied by infrared dichroism as a function of the stretch ratio. Electrical conductivity data of FeCl3-doped PPV films obtained between 80 and 300 K provides evidence that conduction occurs by variable-range hopping in unstretched films and by fluctuation induced tunneling in highly stretched films. The room temperature conductivity parallel sigma(parallel-to) and perpendicular sigma(perpendicular-to) to the stretch direction shows an anisotropy sigma(parallel-to)/sigma(perpendicular-to) equal to 13.

引用

页码：3538 / 3543

页数：6

共 7 条

[1] MOLECULAR-ORIENTATION AND CONDUCTIVITY IN HIGHLY DRAWN POLY(P-PHENYLENE VINYLENE)
GAGNON, DR
KARASZ, FE
THOMAS, EL
LENZ, RW
[J]. SYNTHETIC METALS, 1987, 20 (01) : 85 - 95
[2] ELECTRON HOPPING CONDUCTION IN THE SOLITON MODEL OF POLYACETYLENE
KIVELSON, S
[J]. PHYSICAL REVIEW LETTERS, 1981, 46 (20) : 1344 - 1348
[3] PREPARATION OF POLY(PHENYLENE VINYLENE) FROM CYCLOALKYLENE SULFONIUM SALT MONOMERS AND POLYMERS
LENZ, RW
HAN, CC
STENGERSMITH, J
KARASZ, FE
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1988, 26 (12) : 3241 - 3249
[4] MOLECULAR-ORIENTATION OF HIGHLY DRAWN POLY(PARA-2-METHOXYPHENYLENE VINYLENE)
LIANG, WB
KARASZ, FE
[J]. POLYMER, 1991, 32 (13) : 2363 - 2366
[5] TEMPERATURE-DEPENDENCE OF THE ELECTRICAL-CONDUCTIVITY OF ASF5-DOPED POLY(P-PHENYLENE VINYLENE)
MADSEN, JM
JOHNSON, BR
HUA, XL
HALLOCK, RB
MASSE, MA
KARASZ, FE
[J]. PHYSICAL REVIEW B, 1989, 40 (17): : 11751 - 11755
[6] MERTENS R, IN PRESS SYNTH MET
[7] FLUCTUATION-INDUCED TUNNELING CONDUCTION IN DISORDERED MATERIALS
SHENG, P
[J]. PHYSICAL REVIEW B, 1980, 21 (06): : 2180 - 2195

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