N-ALKYL-3-VINYLPYRIDINIUM SALTS - HOMOPOLYMERIZATION OF THE HEXADECYL DERIVATIVE AND BEHAVIOR STUDY OF THE POLYMER IN AQUEOUS-MEDIA

被引：16

作者：

BENJELLOUN, A ^{[1
]}

DAMAS, C ^{[1
]}

BREMBILLA, A ^{[1
]}

LOCHON, P ^{[1
]}

机构：

[1] INPL,ENSIC,CNRS,CHIM PHYS MARCROMOLEC LAB,1 RUE GRANDVILLE,BP 451,F-54001 NANCY,FRANCE

来源：

POLYMER BULLETIN | 1994年 / 33卷 / 05期

关键词：

Benzene - Derivatives - Dyes - Free radical polymerization - Salts - Solutions - Viscosity measurement;

D O I：

10.1007/BF00296158

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report on the preparation and the characterization of R-alkylated quaternary salts (with R = CH3, C12H25, C16H33, X = Br-) derived from 3-vinylpyridine (3-VP). Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.

引用

页码：513 / 520

页数：8

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