OXYBENZIPORPHYRIN, A FULLY AROMATIC SEMIQUINONE PORPHYRIN ANALOG WITH PATHWAYS FOR 18-PI-ELECTRON DELOCALIZATION

被引：163

作者：

LASH, TD

机构：

[1] Department of Chemistry, Illinois State University, Normal, Illinois

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 22期

关键词：

AROMATICITY; KETO-ENOL TAUTOMERISM; PORPHYRINOIDS;

D O I：

10.1002/anie.199525331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydroxyl substituent makes it happen! Unlike the nonaromatic benziporphyrin 1a (X = H), the hydroxy compound 1b (X = OH) favors the fully aromatic semiquinone tautomer 2. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2533 / 2535

页数：3

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