HIGH-RESOLUTION PHOTOELECTRON-SPECTRA OF DEUTERATED ETHYLENES

被引：31

作者：

CVITAS, T ^{[1
]}

GUSTEN, H ^{[1
]}

KLASINC, L ^{[1
]}

机构：

[1] KERNFORSCHUNGSZENTRUM KARLSRUHE, INST RADIOCHEM, D-7500 KARLSRUHE, GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 01期

关键词：

D O I：

10.1063/1.437174

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high resolution Hei photoelectron spectra of ethylene and five of its deuterated derivatives (CH2CHD, CH2CD2, eis- and trans-CHDCHD, and CD2CD2) have been recorded and the vibrational bands in the first systems of the molecular ions have been assigned. The anomalous deuterium shifts have been explained by Fermi resonance between ν2 and ν3 levels in CH2CH2 and cis-CHDCHD. The PE spectra of cis- and trans-CHDCHD were found to be different supporting the D2 symmetry of the molecular ion. © 1979 American Institute of Physics.

引用

页码：57 / 60

页数：4

共 13 条

[1]

Baker A.D., 1968, INT J MASS SPECTROM, V1, P285

[2] PHOTOELECTRON SPECTRA OF SOME POLYATOMIC MOLECULES [J].

BRANTON, GR ;

FROST, DC ;

MAKITA, T ;

MCDOWELL, CA ;

STENHOUSE, IA .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1970, 268 (1184) :77-+

[3] VIBRATIONAL STRUCTURE IN PHOTOELECTRON SPECTRA OF ETHYLENE AND ETHYLENE-D4, AND ITS RELATIONSHIP TO VIBRATIONAL SPECTRUM OF ZEISES SALT K[PTCL3(C2H4)] H2O [J].

BRUNDLE, CR ;

BROWN, DB .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1971, A 27 (12) :2491-&

[4] THE POTENTIAL FUNCTION OF ETHYLENE [J].

CRAWFORD, BL ;

LANCASTER, JE ;

INSKEEP, RG .

JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (04) :678-686

[5] NEW EXPERIMENTAL TESTS OF EXISTING INTERPRETATIONS OF ELECTRONIC-TRANSITIONS OF ETHYLENE [J].

FOO, PD ;

INNES, KK .

JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (11) :4582-4589

[6] VIBRATIONAL SPECTRA OF SEVERAL PLATINUM-ETHYLENE COMPLEXES - K[PTCL3(C2H4)].H2O (ZEISES SALT) K[PTCL3(C2D4)].H2O AND [PTCL2(C2H4)]2 [J].

HIRAISHI, J .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1969, A 25 (04) :749-&

[7] ELECTRONIC STRUCTURE OF IONIZED MOLECULES .7. ETHYLENE [J].

LORQUET, AJ ;

LORQUET, JC .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (11) :4955-&

[8]

MCDIARMID R, COMMUNICATION

[9] ULTRAVIOLET SPECTRA AND EXCITED STATES OF ETHYLENE AND ITS ALKYL DERIVATIVES [J].

MERER, AJ ;

MULLIKEN, RS .

CHEMICAL REVIEWS, 1969, 69 (05) :639-&

[10] EXCITED-STATES OF ETHYLENE [J].

MULLIKEN, RS .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (06) :2448-2451

← 1 2 →