CYCLIC MESO-IONIC COMPOUNDS .7. ELECTRIC DIPOLE MOMENTS OF SOME MESO-IONIC 1,3,4-THIADIAZOLES

被引：6

作者：

ATKIN, CW

BARNES, ANM

EDGERLEY, PG

SUTTON, LE

机构：

[1] Physical Chemistry Laboratory, Oxford OX1 3QZ, South Parks Road

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 09期

关键词：

D O I：

10.1039/j29690001194

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electric dipole moments of some meso-ionic 1,3,4-thiadiazoles and three similar compounds, with either endo- or exo-sulphur replaced by oxygen, have been measured and analysed to give the magnitude and direction of the thiadiazole ring system moment. The results support the formulation of these compounds as meso-ionic and show that exocyclic sulphur carries a larger negative charge than does exocyclic oxygen.

引用

页码：1194 / &

共 16 条

[1] CYCLIC MESO-IONIC COMPOUNDS .4. PSI-4-ARYL-2-4-DIHYDRO-2-THIO-1-THIA-3-4-DIAZOLES (ENDOTHIODIHYDROTHIODIAZOLES)
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[8] ON THE EVALUATION OF ELECTRIC DIPOLE MOMENTS
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[9] CYCLIC MESO-IONIC COMPOUNDS .2. THE ELECTRIC DIPOLE MOMENTS OF SOME SYDNONES
HILL, RAW
SUTTON, LE
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1949, (MAR): : 746 - 753
[10] CYCLIC MESO-IONIC COMPOUNDS .5. FURTHER STUDIES ON THE STEREOCHEMISTRY OF THE SYDNONES, WITH A DESCRIPTION OF A HETERODYNE CAPACITANCE METER FOR DIELECTRIC-CONSTANT MEASUREMENTS IN THE RANGE 2-3
HILL, RAW
SUTTON, LE
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1953, (MAY): : 1482 - 1490

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