A NEW SYNTHESIS OF HINDERED UNSYMMETRICAL TERT-ALKYL ETHERS

被引：7

作者：

MASADA, H

GOTOH, H

OHKUBO, M

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 10期

关键词：

D O I：

10.1246/cl.1991.1739

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual Williamson reactions of t-butyl and t-pentyl halides with lithium t-alkoxides or with t-alkyl alcohols and amines were carried out at 20-50-degrees-C. Some of the nucleophilic substitution products were new unsymmetrical ethers: t-butyl t-pentyl ether, t-butyl 1,1-dimethyl-2-propenyl ether, t-butyl 1,1-dimethyl-2-propynyl ether, 1,1-dimethyl-2-propynyl t-pentyl ether, and t-butyl 1-ethyl-1-methyl-2-propynyl ether.

引用

页码：1739 / 1742

页数：4