A NOVEL HYBRID SYSTEM FOR THE DIRECT OXIDATION OF ETHANE TO ACETIC AND GLYCOLIC ACIDS IN AQUEOUS-MEDIUM

被引：25

作者：

SEN, AM

LIN, MR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of platinum(II) ion and metallic platinum is found to oxidise ethane to a mixture of acetic and glycolic acids in aqueous medium in the presence of oxygen; the platinum(II) ion is responsible for the initial C-H activation step leading eventually to the formation of ethanol and ethylene glycol, while metallic platinum catalyses the subsequent air oxidation of the alcohols to the corresponding acids.

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页码：508 / 510

页数：3

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