EFFECT OF TEMPERATURE ON THE DISSOCIATIVE AND NONDISSOCIATIVE ELECTRON-ATTACHMENT TO FREONS

被引:4
作者
CHRISTOPHOROU, LG
DATSKOS, PG
CARTER, JG
机构
[1] OAK RIDGE NATL LAB, ATOM MOLEC & HIGH VOLTAGE PHYS GRP HLTH, OAK RIDGE, TN 37831 USA
[2] OAK RIDGE NATL LAB, DIV SAFETY RES, OAK RIDGE, TN 37831 USA
[3] UNIV TENNESSEE, DEPT PHYS, KNOXVILLE, TN 37996 USA
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1992年 / 96卷 / 03期
关键词
ELECTROCHEMISTRY; ELEMENTARY REACTIONS; GASES; MASS SPECTROMETRY; RADIATION CHEMISTRY;
D O I
10.1002/bbpc.19920960342
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The attachment of slow electrons to freons (including many atmospheric halocarbons) depends rather strongly on the gas temperature. In general, as the temperature increases, dissociative electron attachment increases and nondissociative electron attachment decreases; the former behavior is principally due to increase in autodissociation and the latter principally due to increase in autodetachment of the transient anion.
引用
收藏
页码:448 / 450
页数:3
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CHRISTOPHOROU LG, 1984, ELECTRON MOL INTERAC, V1, pCH6
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CHRISTOPHOROU LG, IN PRESS 20TH INT C
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