SYNTHESIS, CHARACTERIZATION AND PHOTOPHYSICS OF LUMINESCENT ORGANOGOLD(I) PHOSPHINES

被引：37

作者：

YAM, VWW

CHOI, SWK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 14期

关键词：

D O I：

10.1039/dt9940002057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organolithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3] in high yield [dmpm = MePCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential of -2.0(1) V vs. sodium chloride saturated calomel electrode has been estimated for [Au3(dmmp)(C6H4OMe-p)3].

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页码：2057 / 2059

页数：3

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