MEASUREMENTS OF H2O2 DURING WATOX-86

被引：25

作者：

Heikes, B. ^{[1
]}

Walega, J. ^{[1
]}

Kok, G. ^{[1
]}

Lind, J. ^{[1
]}

Lazrus, A. ^{[1
]}

机构：

[1] Natl Ctr Atmospher Res, Boulder, CO USA

来源：

GLOBAL BIOGEOCHEMICAL CYCLES | 1988年 / 2卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1029/GB002i001p00057

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Measurements of gas phase H2O2 were made on all Western Atlantic Ocean Experiment 1986 (WATOX-86) flights aboard the National Oceanic and Atmospheric Administration (NOAA) WP-3D aircraft. These were some of the first airborne real-time H2O2 measurements made in winter. Operation of the instru-ment was limited to altitude < 3.1 km with a detection limit, determined by interference considerations, of 0.05 parts per billion by volume (ppbv), 10% calibration accuracy and 0.03-ppbv precision. Experimental measurements showed the mean H2O2 to be 0.12 ppbv (standard deviation = 0.07, maximum = 1.2 ppbv). Vertical structure was observed with maximum H2O2 above the cloud-capped marine boundary layer. Boundary layer H2O2 was typically at or below the detection limit.

引用

收藏

页码：57 / 61

页数：5

相关论文

共 16 条

[1] CHEMICAL MECHANISMS OF ACID GENERATION IN THE TROPOSPHERE [J].

CALVERT, JG ;

LAZRUS, A ;

KOK, GL ;

HEIKES, BG ;

WALEGA, JG ;

LIND, J ;

CANTRELL, CA .

NATURE, 1985, 317 (6032) :27-35

[2] AVERAGE CONCENTRATIONS OF OH IN TROPOSPHERE, AND BUDGETS OF CH4 CO H-2 + CH3CCL3 [J].

CRUTZEN, PJ ;

FISHMAN, J .

GEOPHYSICAL RESEARCH LETTERS, 1977, 4 (08) :321-324

[3]

Galloway J. N., 1987, GLOBAL BIOG IN PRESS, V1

[4] DEPENDENCE ON H2O AND ON NH3 OF KINETICS OF SELF-REACTION OF HO2 IN GAS-PHASE FORMATION OF HO2.H2O AND HO2.NH3 COMPLEXES [J].

HAMILTON, EJ ;

LII, RR .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1977, 9 (06) :875-885

[5] H2O2, O-3 AND SO2 MEASUREMENTS IN THE LOWER TROPOSPHERE OVER THE EASTERN-UNITED-STATES DURING FALL [J].

HEIKES, BG ;

KOK, GL ;

WALEGA, JG ;

LAZRUS, AL .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D1) :915-931

[6] AUTOMATED FLUOROMETRIC METHOD FOR HYDROGEN-PEROXIDE IN ATMOSPHERIC PRECIPITATION [J].

LAZRUS, AL ;

KOK, GL ;

GITLIN, SN ;

LIND, JA ;

MCLAREN, SE .

ANALYTICAL CHEMISTRY, 1985, 57 (04) :917-922

[7] AUTOMATED FLUOROMETRIC METHOD FOR HYDROGEN-PEROXIDE IN AIR [J].

LAZRUS, AL ;

KOK, GL ;

LIND, JA ;

GITLIN, SN ;

HEIKES, BG ;

SHETTER, RE .

ANALYTICAL CHEMISTRY, 1986, 58 (03) :594-597

[8] OZONE PRODUCTION IN THE RURAL TROPOSPHERE AND THE IMPLICATIONS FOR REGIONAL AND GLOBAL OZONE DISTRIBUTIONS [J].

LIU, SC ;

TRAINER, M ;

FEHSENFELD, FC ;

PARRISH, DD ;

WILLIAMS, EJ ;

FAHEY, DW ;

HUBLER, G ;

MURPHY, PC .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D4) :4191-4207

[9] TROPOSPHERIC CHEMISTRY - A GLOBAL PERSPECTIVE [J].

LOGAN, JA ;

PRATHER, MJ ;

WOFSY, SC ;

MCELROY, MB .

JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1981, 86 (NC8) :7210-7254

[10]

Luke W. T., 1987, GLOBAL BIOGEOCHEM CY