CRYSTAL-STRUCTURE OF A PHENYLIMINOMETHYLDICYCLOPENTADIENYLTITANIUM(III) COMPLEX, CP2TI-ETA-2-C6H5CN-2,6-(CH3)2C6H3

被引:33
作者
VANBOLHUIS, F [1 ]
DEBOER, EJM [1 ]
TEUBEN, JH [1 ]
机构
[1] UNIV GRONINGEN, ANORGAN CHEM LAB, NL-9747 AG GRONINGEN, NETHERLANDS
关键词
D O I
10.1016/S0022-328X(00)92068-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structure of Cp2TiC6H5CN-2,6-(CH3)2C6H3 is reported. The iminoacyl ligand is η2-coordinated at the metal (TiC 2.096(4), TiN 2.149(4) Å). The cyclopentadienyl ligands show the normal bent Cp2Ti structure. © 1979.
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页码:299 / 308
页数:10
相关论文
共 19 条
[1]   ISOCYANIDE INSERTION REACTIONS .2. STRUCTURAL AND DYNAMICAL STEREOCHEMISTRY OF ETA-1-IMINOACYL AND ETA-2-IMINOACYL LIGANDS [J].
ADAMS, RD ;
CHODOSH, DF .
INORGANIC CHEMISTRY, 1978, 17 (01) :41-48
[2]   UNUSUAL COORDINATION BEHAVIOR OF IMINOALKYL LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF "(MU-H)OS3(CO)10(MU-ETA-2-C6H5CNCH3) [J].
ADAMS, RD ;
GOLEMBESKI, NM .
INORGANIC CHEMISTRY, 1978, 17 (07) :1969-1973
[3]   MOLECULAR-STRUCTURE OF 1,1-BIS(ETA-5-CYCLOPENTADIENYL)-2,3,4,5-TETRAPHENYLTITANOLE AND ITS HAFNIUM ANALOG [J].
ATWOOD, JL ;
HUNTER, WE ;
ALT, H ;
RAUSCH, MD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) :2454-2459
[4]  
BOER EJM, 1979, J ORGANOMET CHEM, V166, P193
[5]   MOLECULAR CONFORMATION OF BENZYLIDENEANILINES - RELATION TO ELECTRONIC STRUCTURE AND SPECTRA [J].
BURGI, HB ;
DUNITZ, JD .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (09) :472-&
[6]   X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].
CROMER, DT ;
MANN, JB .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&
[7]   NOVEL BONDING MODE OF DIPHENYLKETENE TO A TRANSITION-METAL - METAL ANCHORED OLEFIN SYSTEM [J].
FACHINETTI, G ;
BIRAN, C ;
FLORIANI, C ;
CHIESIVILLA, A ;
GUASTINI, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (06) :1921-1922
[8]  
FACHINETTI G, 1977, J CHEM SOC DA, P2298
[9]   APPLICATION OF PHASE RELATIONSHIPS TO COMPLEX STRUCTURES .3. OPTIMUM USE OF PHASE RELATIONSHIPS [J].
GERMAIN, G ;
MAIN, P ;
WOOLFSON, MM .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1971, A 27 (JUL1) :368-&
[10]   ON SOME ERRORS IN X-RAY ANALYSIS .1. SYSTEMATIC ERRORS IN OBSERVED STRUCTURE FACTORS [J].
JELLINEK, F .
ACTA CRYSTALLOGRAPHICA, 1958, 11 (10) :677-679