LONG-RANGE QUENCHING OF TRIPLET PHENANTHRENE BY COPPER IONS IN THE LIQUID-PHASE

被引:8
作者
BUTLER, PR
PILLING, MJ
机构
[1] Physical Chemistry Laboratory, Oxford, OX1 3QZ, South Parks Road
关键词
D O I
10.1016/0301-0104(79)85073-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The quenching of triplet phenanthiene by Cu2+ has been studied over a range of high viscosities. The rate constants were determined in the time-dependent regime and are compatible with an encounter distance which increases with increasing viscosity. The Smoluchowski analysis of the time-dependence breaks down at very high viscosities in agreement with a numerical analysis. © 1979.
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页码:33 / 36
页数:4
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